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An improved synthesis of Kagan's menthyl substituted titanocene and zirconocene dichloride, comparison of their crystal structures, and preliminary catalyst evaluation
OtherAbstract: An improved synthesis of 1 and 2 is described that allows access to these complexes in multigram quaPalabras claves:Carbometallation, Catalysis, Crystal structure, titanium, ZirconiumAutores:Antonio Rosales Martínez, Bluhm H., Cuerva J.M., Gansäuer A., Narayan S., Nieger M., Oltra J.E., Schiffer-Ndene N.Fuentes:scopusCatalytic epoxypolyene cyclization via radicals: Highly diastereoselective formal synthesis of puupehedione and 8-epi-puupehedione
ArticleAbstract: A catalytic and highly stereoselective synthesis of a common building block for the marine natural pPalabras claves:Catalysis, Cuprates, Epoxypolyene cyclization, Natural productsAutores:Antonio Rosales Martínez, Gansäuer A., Justicia J.Fuentes:scopusEfficient and stereoselective synthesis of precursors for epoxypolyene cyclizations via allylic substitutions
ArticleAbstract: A catalytic and highly stereoselective approach to precursors for epoxypolyene cyclizations based onPalabras claves:Catalysis, Cuprates, Epoxides, Epoxypolyene cyclization, Grignard ReagentAutores:Antonio Rosales Martínez, Gansäuer A., Justicia J., Rinker B.Fuentes:scopusHydrogen atom donors: Recent developments
ReviewAbstract: This review highlights recent developments in the field of hydrogen atom transfer (HAT) reagents thaPalabras claves:Bond dissociation energies, Catalysis, Chain reactions, Hydrogen atom transfer, Metal-hydrogen bonds, radicalsAutores:Antonio Rosales Martínez, Gansäuer A., Huth I., Oltra J.E., Otte M., Padial N.M., Sancho-Sanz I., Shi L.Fuentes:scopus