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A concise route for the synthesis of tetracyclic meroterpenoids: (±)-aureol preparation and mechanistic interpretation
ArticleAbstract: A new concise general methodology for the synthesis of different tetracyclic meroterpenoids is reporPalabras claves:Aureol, Natural products synthesis, Tetracyclic meroterpenoidsAutores:Antonio Rosales Martínez, Díaz Ojeda E., Enríquez L., Jaraíz M., Pozo-Morales L., Rodríguez-García I.Fuentes:scopusA convenient cross-metathesis approach to trisporins
ArticleAbstract: Three series of trisporins have been prepared using a strategy in which a cross-metathesis is the kePalabras claves:Autores:Alvarez-Corral M., Antonio Rosales Martínez, Hernández-Cervantes C., López-Sánchez C., Muñoz-Dorado M., Rodríguez-García I.Fuentes:scopusDiastereoselective Synthesis of (±)-Ambrox by Titanium(III)-Catalyzed Radical Tandem Cyclization
ArticleAbstract: A synthesis of (±)-ambrox, a compound with delicious ambergris-type scent, is presented. The key stePalabras claves:ambrox, diastereoselective synthesis, Natural products, radical chemistry, TitanoceneAutores:Antonio Rosales Martínez, Foley L.A.R., Irías-Álvarez A., Muñoz-Bascón J., Oltra J.E., Padial N.M., Pozo-Morales L., Rodríguez-García I., Roldan-Molina E., Roman Nicolay Rodríguez-Maecker, Sancho-Sanz I.Fuentes:scopusCp<inf>2</inf> TiCl/D<inf>2</inf> O/Mn, a formidable reagent for the deuteration of organic compounds
ReviewAbstract: Cp2 TiCl/D2 O/Mn is an efficient combination, sustainable and cheap reagent that mediates the D-atomPalabras claves:Deuteration, Deuterium atom transfer, Radical and/or organometallic chemistry, TitanoceneAutores:Antonio Rosales Martínez, Rodríguez-García I.Fuentes:scopusCp<inf>2</inf>TiCl: An Ideal Reagent for Green Chemistry?
ArticleAbstract: The development of Green Chemistry inevitably involves the development of green reagents. In this rePalabras claves:Autores:Antonio Rosales Martínez, Castro Rodríguez M., Oltra J.E., Pozo-Morales L., Rodríguez-García I., Roman Nicolay Rodríguez-MaeckerFuentes:scopusGreen Reductive Regioselective Opening of Epoxides: A Green Chemistry Laboratory Experiment
ArticleAbstract: Green chemistry is finding its place as one of the most essential study topics in the curriculum ofPalabras claves:Green Chemistry, laboratory instruction, reductive opening of epoxides, TitanoceneAutores:Antonio Rosales Martínez, López-Martínez J.L., Rodríguez-García I.Fuentes:scopusErratum: The Nugent-RajanBabu Reagent: A Formidable Tool in Contemporary Radical and Organometallic Chemistry (European Journal of Organic Chemistry (2015) (4567-4591))
OtherAbstract:Palabras claves:Metallocenes, Nugent reagent, Organometallic chemistry, Radical reactions, titaniumAutores:Antonio Rosales Martínez, García-Ocaña M., Muñoz-Bascón J., Oltra J.E., Padial N.M., Pozo-Morales L., Rodríguez-García I., Roldan-Molina E.Fuentes:scopusDivergent strategy in marine tetracyclic meroterpenoids synthesis
ReviewAbstract: The divergent total synthesis strategy can be successfully applied to the preparation of families ofPalabras claves:Aureol, Divergent total synthesis, marine natural products, Tetracyclic meroterpenoidsAutores:Antonio Rosales Martínez, López-Martínez J.L., Rodríguez-García I.Fuentes:scopusUnderstanding the color change of the solutions of Cp<inf>2</inf>TiCl upon addition of water
ArticleAbstract: Reduction of red bis (cyclopentadienyl)titanium (IV) dichloride (Cp2TiCl2) with manganese dust in drPalabras claves:colorimetric indicator, hydrogen atom transfer reagent, radical chemistry, TitanoceneAutores:Antonio Rosales Martínez, Enríquez L., Jaraíz M., McIndoe J.S., Rodríguez-García I., Sidhu J., Thiessen T.Fuentes:scopusUnifying the Synthesis of a Whole Family of Marine Meroterpenoids through a Biosynthetically Inspired Sequence of 1,2-Hydride and Methyl Shifts as Key Step
ArticleAbstract: Marine meroterpenoids have attracted a great deal of attention from synthetic research groups due toPalabras claves:marine natural products, meroterpenoids, rearrangements, synthetic strategiesAutores:Antonio Rosales Martínez, Rodríguez-García I., Roman Nicolay Rodríguez-MaeckerFuentes:scopus