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Journal of Organic Chemistry(4)
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Química orgánica(21)
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scopus(24)
Asymmetric Reduction of Ketones
Book PartAbstract:Palabras claves:Arene ruthenium complex with polymerizable side chains, Chiral trivalent phosphorus compounds, Ketone asymmetric reduction, Late transition metal ligands in homogeneous catalysis, Polymer-supported chiral sulfonamide catalyzed reduction, Ruthenium-catalyzed hydrogenation -synphos and difluorphos ligands, Titanocene-catalyzed ketone reductionAutores:Adolfsson H., Antonio Rosales Martínez, Börner A., Burri E., Chai L., Cuerva J.M., Docherty G., Dubrovina N., Fujii M., Genet J.P., Guo M., Henschke J.P., Ida Y., Jeulin S., Lennon I.C., Li D., Li Y., Mohar B., Moran P.H., Nakamura K., Oltra J.E., Ratovelomanana-Vidal V., Severin K., Stephan M., Sun Y., Wang G., Wang Q., Wendicke S.B., Wettergren J., Wills M., Woodward G., Xu Y., Zanotti-Gerosa A., Zhang Z., Zhao G.Fuentes:scopusA convenient cross-metathesis approach to trisporins
ArticleAbstract: Three series of trisporins have been prepared using a strategy in which a cross-metathesis is the kePalabras claves:Autores:Alvarez-Corral M., Antonio Rosales Martínez, Hernández-Cervantes C., López-Sánchez C., Muñoz-Dorado M., Rodríguez-García I.Fuentes:scopusDiastereoselective Synthesis of (±)-Ambrox by Titanium(III)-Catalyzed Radical Tandem Cyclization
ArticleAbstract: A synthesis of (±)-ambrox, a compound with delicious ambergris-type scent, is presented. The key stePalabras claves:ambrox, diastereoselective synthesis, Natural products, radical chemistry, TitanoceneAutores:Antonio Rosales Martínez, Foley L.A.R., Irías-Álvarez A., Muñoz-Bascón J., Oltra J.E., Padial N.M., Pozo-Morales L., Rodríguez-García I., Roldan-Molina E., Roman Nicolay Rodríguez-Maecker, Sancho-Sanz I.Fuentes:scopusCp<inf>2</inf> TiCl/D<inf>2</inf> O/Mn, a formidable reagent for the deuteration of organic compounds
ReviewAbstract: Cp2 TiCl/D2 O/Mn is an efficient combination, sustainable and cheap reagent that mediates the D-atomPalabras claves:Deuteration, Deuterium atom transfer, Radical and/or organometallic chemistry, TitanoceneAutores:Antonio Rosales Martínez, Rodríguez-García I.Fuentes:scopusCatalytic epoxypolyene cyclization via radicals: Highly diastereoselective formal synthesis of puupehedione and 8-epi-puupehedione
ArticleAbstract: A catalytic and highly stereoselective synthesis of a common building block for the marine natural pPalabras claves:Catalysis, Cuprates, Epoxypolyene cyclization, Natural productsAutores:Antonio Rosales Martínez, Gansäuer A., Justicia J.Fuentes:scopusEnantiospecific strategy towards oxygen-bridged terpenoids: Tandem transannular-cyclization and ring-contraction processes
ArticleAbstract: From conformational flexibility to rigidity: The straightforward synthesis of rigid molecules with aPalabras claves:Carbocycles, Cyclization, Epoxidation, Ring contraction, synthetic methodsAutores:Antonio Rosales Martínez, Cuerva J.M., Estévez R.E., Oltra J.E.Fuentes:scopusErratum: The Nugent-RajanBabu Reagent: A Formidable Tool in Contemporary Radical and Organometallic Chemistry (European Journal of Organic Chemistry (2015) (4567-4591))
OtherAbstract:Palabras claves:Metallocenes, Nugent reagent, Organometallic chemistry, Radical reactions, titaniumAutores:Antonio Rosales Martínez, García-Ocaña M., Muñoz-Bascón J., Oltra J.E., Padial N.M., Pozo-Morales L., Rodríguez-García I., Roldan-Molina E.Fuentes:scopusEffects of solvents and water in Ti(III)-mediated radical cyclizations of epoxygermacrolides. Straightforward synthesis and absolute stereochemistry of (+)-3α-hydroxyreynosin and related eudesmanolides
ArticleAbstract: The Cp2TiCl-mediated rearrangement of 1,10-epoxy-11β,13-dihydrocostunolide (4) was carried out usingPalabras claves:Autores:Antonio Rosales Martínez, Barrero A.F., Cuerva J.M., Enrique Oltra J.Fuentes:scopusEfficient and stereoselective synthesis of precursors for epoxypolyene cyclizations via allylic substitutions
ArticleAbstract: A catalytic and highly stereoselective approach to precursors for epoxypolyene cyclizations based onPalabras claves:Catalysis, Cuprates, Epoxides, Epoxypolyene cyclization, Grignard ReagentAutores:Antonio Rosales Martínez, Gansäuer A., Justicia J., Rinker B.Fuentes:scopusTransition-metal-catalyzed allylic substitution and titanocene-catalyzed epoxypolyene cyclization as a powerful tool for the preparation of terpenoids
ArticleAbstract: Many biologically active substances are composed of sesquiterpene units linked to aromatic structurePalabras claves:Copper, Cyclization, Epoxides, radicals, titaniumAutores:Antonio Rosales Martínez, Cuerva J.M., Gansäuer A., Justicia J., Oltra J.E., Rinker B., Worgull D.Fuentes:scopus