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Chemistry of N-functionalized spirodihydroquinolines. Unusual access to the 3-methyl-4-(2-oxo-pyrrolidinyl-1)spiro[indane-1,1′-cyclohexanes] from 1-(3-cyanopropyl)-3,4-dihydrospiro[quinoline-2,1′-cyclohexanes]
ArticleAbstract: The transformation of N-substituted 3,4-dihydrospiro[quinoline-2,1′-cyclohexanes] 2 and 3 has been ePalabras claves:Aminospiroindanes, Intramolecular Friedel-Crafts alkylation, SpirodihydroquinolinesAutores:Bahsas A., Juan Manuel Amaro-Luis, Kouznetsov V.V., Palma A., Rozo W., Stashenko E.E.Fuentes:scopus2-Allyl-N-benzyl substituted α-naphthylamines as building blocks in heterocyclic synthesis. New and efficient syntheses of benz[e]naphtho[1,2-b]azepine and naphtho[1,2-b]azepine derivatives
ArticleAbstract: A new series of 13-acetyl-7,12-dihydro-7-ethylbenz[e]naphtho[1,2-b]azepine (4a-d) and 2-aryl-4-hydroPalabras claves:Amino-Claisen rearrangement, Benz[e]naphtho[1,2-b]azepines, Intramolecular dipolar 1,3-cycloaddition, Intramolecular Friedel-Crafts alkylation, Tetrahydronaphtho[1,2-b]azepinesAutores:Bahsas A., Juan Manuel Amaro-Luis, Palma A., Stashenko E.E., Yépez A.Fuentes:scopusA facile Brönsted acidic-mediated cyclisation of 2-allyl-1-arylaminocyclohexanes to octahydroacridine derivatives
ArticleAbstract: The classical acidic cyclisation has been used for the preparation of new substituted octahydroacridPalabras claves:Autores:Bahsas A., Juan Manuel Amaro-Luis, Kouznetsov V.V., Palma A., Rozo W., Stashenko E.E.Fuentes:scopusA simple and efficient preparation of 3,4-dialkylsubstituted tetrahydroisoquinoline using cyclopropylethyliden benzylamine
ArticleAbstract: Intramolecular Friedel-Crafts alkylation of N-benzyl-N-(1-cyclopropylethyl)acetamide to 3,4-dialkylPalabras claves:Autores:Bahsas A., Juan Manuel Amaro-Luis, Kouznetsov V.V., Palma A., Rozo W., Stashenko E.E.Fuentes:scopusNew and efficient synthesis of 6,11-dihydro-11-ethyl-5H-dibenz[b,e]azepine derivatives starting from N-benzylanilines via amino-Claisen and Friedel-Crafts methodologies
ArticleAbstract: New and efficient synthesis of 6,11-dihydro-11-ethyl-5H-dibenz[b,e]azepine derivatives, using the kePalabras claves:Amino-Claisen rearrangement, Dibenz[b,e]azepine derivatives, Intramolecular alkene Friedel-Crafts alkylation, N-allylationAutores:Bahsas A., Barajas J., Juan Manuel Amaro-Luis, Kouznetsov V.V., Palma A., Stashenko E.E.Fuentes:scopusUnexpected and novel synthesis of spirojulolidines via intramolecular cyclization of N-carbethoxymethyl spirotetrahydroquinolines catalyzed by PPA
ArticleAbstract: A series of N-carbethoxymethyl spirotetrahydroquinolines (6) were prepared and subjected to cyclizatPalabras claves:Intramolecular alkylation, Spirojulolidine, SpirolilolidineAutores:Bahsas A., Carrillo C., Juan Manuel Amaro-Luis, Kouznetsov V.V., Palma A., Stashenko E.E.Fuentes:scopusSequential amino-Claisen rearrangement/intramolecular 1,3-dipolar cycloaddition/reductive cleavage approach to the stereoselective synthesis of cis-4-hydroxy-2-aryl-2,3,4,5-tetrahydro-1(1H)-benzazepines
ArticleAbstract: A novel stereoselective synthesis of cis-2-aryl-4-hydroxy-2,3,4,5- tetrahydro-1-benzazepines from N-Palabras claves:Amino-Claisen rearrangement, Intramolecular 1,3-dipolar cycloaddition, Ortho-allylanilines, Reductive cleavage, Tetrahydro-1-benzazepinesAutores:Ayala S., Bahsas A., Juan Manuel Amaro-Luis, Palma A., Stashenko E.E.Fuentes:scopusStudies directed to the synthesis of new C-5 spiroannulated julolidines
ArticleAbstract: Two series of new 7,9-disubstituted spirojulolidines 8a-d and 10a-e were synthesized by acid catalyzPalabras claves:Intramolecular Friedel-Crafts alkylation, Spirojulolidine, SpirolilolidineAutores:Bahsas A., Carrillo C., Juan Manuel Amaro-Luis, Kouznetsov V.V., Palma A., Silva Agredo J., Stashenko E.E.Fuentes:scopus